correct me if im wrong, always convert it into meters/seconds when doing physics, just divde it by 3.6
g=ground velocity
a=airplane velocity
w= wind velocity
the general equation would be V(g)=V(a)+V(w)
since they're on angles you would have to split them up into 2 components x and y so;
x; V(g)= 138.8cos(180-45)+33.3cos(180+25)
y; V(g)= 138.8sin(180-45)+33.3sin(180+25)
solve them when you get both components you will have to find the vector between them so;
|V(g)|=sqr(t(x^2+y^2))
and you should get your vector
hope it helped :)