"when 100 g of liquid water initally at a temperature of 33 c freezes, the entropy of the water:
A.decreases
B.does not change
C.could either increase or decrease it depends on other factors
D. increases"
In order for the water to reduce in temperature it must lose heat to it's surroundings. The entropy of the water will decrease and that of the surroundings will increase.
The heat lost by the water = the heat gained by its surroundings, but, since the surroundings must be at a lower temperature to start with, the entropy of the surroundings will increase by more than the entropy of the water decreases (entropy = heat gained or lost divided by temperature).