You can get a sum of 23 by selecting a 5 from the first set and an 18 from the second set
or selecting a 9 from the first set and a 14 from the second set.
The probability of selecting a 5 from the first set is 1/4 and the probability of selecting an 18 from the second set is 1/5, so the probability of selecting a 5 from the first set and an 18 from the second set is 1/4 x 1/5 or 1/20.
The probability of selecting a 9 from the first set is 1/4 and the probability of selecting a 14 from the second set is 1/5, so the probability of selecting a 9 from the first set and a 14 from the second set is 1/4 x 1/5 or 1/20.
The probability of doing either of these two is found by adding the individual probabilities together: 1/20 + 1/20 = 1/10.
The answer is 1/10.