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Majid

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 #3
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Thanks Alna, for your answer! Yes, I'm sorry for the mistake, I just didn't notice it, it's actually :h=-T(dv/dT) at constant p.

Here's my answer for this question: 

H=U+pv(H is the enthalpy)

H=Q+W+pv(U=Q+W)

dH=dQ+dW+d(pv)

knowing that dQ=CvdT+hdp

dH=CvdT+hdppdv+pdv+vdp

dH=CvdT+hdp+vdp

dH=CvdT+(h+v)dp

H is a state function, that means it's a total  differential:

(Cvp)T=((h+v)T)p

(Cvp)T=(hT)p+(vT)p(1)

On the other hand we have:

dQ=CvdT+hdp(1T)

dS=CvTdT+hTdp

S is a state function, that means it's a total  differential:

((Cv/T)p)T=((h/T)T)p

1T(Cvp)T=T(hT)phT²T²

(Cvp)T=(hT)phT(2)

(1)=(2)

(hT)p+(vT)p=(hT)phT

 

(vT)p=hT

 

h=T(vT)p

.
Jan 15, 2017