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Prove these relations:

(Tp)v.(vT)p=(vp)T

 Jan 14, 2017

Best Answer 

 #2
avatar+33658 
+10

Here's the first part:

 

 

The second part isn't correct:  dv/dp at constant p would be zero!

 Jan 15, 2017
 #1
avatar
0

h=-T[dv/dp]p

 

Solve the separable equation h = -p T(( dv(p))/( dp)):
Solve for ( dv(p))/( dp):
( dv(p))/( dp) = T^(-1) (-h/p)
Integrate both sides with respect to p:
Answer: |v(p) = integral T^(-1) (-h/p) dp = integral T^(-1) (-h/p) dp + c_1, where c_1 is an arbitrary constant.

 Jan 14, 2017
 #2
avatar+33658 
+10
Best Answer

Here's the first part:

 

 

The second part isn't correct:  dv/dp at constant p would be zero!

Alan Jan 15, 2017
 #3
avatar+101 
+5

Thanks Alna, for your answer! Yes, I'm sorry for the mistake, I just didn't notice it, it's actually :h=-T(dv/dT) at constant p.

Here's my answer for this question: 

(H is the enthalpy)

(U=Q+W)

knowing that 

H is a state function, that means it's a total  differential:

(1)

On the other hand we have:

S is a state function, that means it's a total  differential:

(2)

(1)=(2)

 

 

Majid  Jan 15, 2017

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