Draw it up and let the side length of the square be 2. That is an easy number to work with.
Find lengths AC and AP and AQ using Pythagoras's theorem and basic logic.
What is angle ACB ?
Now it is easier to find angle CAP and then double it than it is to find angle QAP.
You can find angle CAP using either sine rule or cosine rule. (the answer will be approx.)
Edit (added): you want sine of it, not the angle itself, so that is easier and it will be exact.
Now Age26 you should have the info you need, if you want to clarify something then ask.
Please no one answer over me.