If tan(α/2) = 3 then α/2 = tan-1(3) and α = 2tan-1(3). Most calculators will give the 1st quadrant value for tan-1(3), so just finding sin(2tan-1(3)) will give the correct result:
$${\mathtt{2}}{\mathtt{\,\times\,}}\underset{\,\,\,\,^{\textcolor[rgb]{0.66,0.66,0.66}{360^\circ}}}{{tan}}^{\!\!\mathtt{-1}}{\left({\mathtt{3}}\right)} = {\mathtt{143.130\: \!102\: \!354\: \!156}}$$
$$\underset{\,\,\,\,^{\textcolor[rgb]{0.66,0.66,0.66}{360^\circ}}}{{sin}}{\left({\mathtt{2}}{\mathtt{\,\times\,}}\underset{\,\,\,\,^{\textcolor[rgb]{0.66,0.66,0.66}{360^\circ}}}{{tan}}^{\!\!\mathtt{-1}}{\left({\mathtt{3}}\right)}\right)} = {\frac{{\mathtt{3}}}{{\mathtt{5}}}} = {\mathtt{0.6}}$$
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If tan(α/2) = 3 then α/2 = tan-1(3) and α = 2tan-1(3). Most calculators will give the 1st quadrant value for tan-1(3), so just finding sin(2tan-1(3)) will give the correct result:
$${\mathtt{2}}{\mathtt{\,\times\,}}\underset{\,\,\,\,^{\textcolor[rgb]{0.66,0.66,0.66}{360^\circ}}}{{tan}}^{\!\!\mathtt{-1}}{\left({\mathtt{3}}\right)} = {\mathtt{143.130\: \!102\: \!354\: \!156}}$$
$$\underset{\,\,\,\,^{\textcolor[rgb]{0.66,0.66,0.66}{360^\circ}}}{{sin}}{\left({\mathtt{2}}{\mathtt{\,\times\,}}\underset{\,\,\,\,^{\textcolor[rgb]{0.66,0.66,0.66}{360^\circ}}}{{tan}}^{\!\!\mathtt{-1}}{\left({\mathtt{3}}\right)}\right)} = {\frac{{\mathtt{3}}}{{\mathtt{5}}}} = {\mathtt{0.6}}$$
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