Let's consider the value of i^x for all possible values of x:
i^1 = i i^2 = -1 i^3 = -i i^4 = 1
As we can see, the value of i^x starts repeating after every 4th power. This means that for any positive integer n, the value of i^n can be expressed as i^(n % 4).
Since 1 ≤ x < y ≤ 100, we have four possibilities for the value of (x % 4) and (y % 4):
(x % 4) = 1, (y % 4) = 3
(x % 4) = 2, (y % 4) = 2
(x % 4) = 3, (y % 4) = 1
(x % 4) = 0, (y % 4) = 0
For the first case, we have 25 pairs of (x, y) where x = 1, 5, 9, ..., 97 and y = 3, 7, 11, ..., 99.
For the second case, we have 25 pairs of (x, y) where x = 2, 6, 10, ..., 98 and y = 2, 6, 10, ..., 98.
For the third case, we have 25 pairs of (x, y) where x = 3, 7, 11, ..., 99 and y = 1, 5, 9, ..., 97.
For the fourth case, we have 24 pairs of (x, y) where x = 4, 8, 12, ..., 100 and y = 4, 8, 12, ..., 100.
Therefore, the total number of pairs of integers (x, y) with 1 ≤ x < y ≤ 100 such that i^x + i^y is a real number is 25 + 25 + 25 + 24 = 99.